/* ---------------------------------------------------------------------- LAMMPS - Large-scale Atomic/Molecular Massively Parallel Simulator http://lammps.sandia.gov, Sandia National Laboratories Steve Plimpton, sjplimp@sandia.gov Copyright (2003) Sandia Corporation. Under the terms of Contract DE-AC04-94AL85000 with Sandia Corporation, the U.S. Government retains certain rights in this software. This software is distributed under the GNU General Public License. See the README file in the top-level LAMMPS directory. ------------------------------------------------------------------------- */ /* ---------------------------------------------------------------------- Contributing author: Georgios G. Vogiatzis (CoMSE, NTU Athens), gvog@chemeng.ntua.gr ------------------------------------------------------------------------- */ #include <mpi.h> #include <cmath> #include <cstdlib> #include "improper_cossq.h" #include "atom.h" #include "comm.h" #include "neighbor.h" #include "domain.h" #include "force.h" #include "update.h" #include "memory.h" #include "error.h" #include "math_const.h" using namespace LAMMPS_NS; using namespace MathConst; #define TOLERANCE 0.05 #define SMALL 0.001 /* ---------------------------------------------------------------------- */ ImproperCossq::ImproperCossq(LAMMPS *lmp) : Improper(lmp) {} /* ---------------------------------------------------------------------- */ ImproperCossq::~ImproperCossq() { if (allocated) { memory->destroy(setflag); memory->destroy(k); memory->destroy(chi); } } /* ---------------------------------------------------------------------- */ void ImproperCossq::compute(int eflag, int vflag) { int i1,i2,i3,i4,n,type; double vb1x,vb1y,vb1z,vb2x,vb2y,vb2z,vb3x,vb3y,vb3z ; double eimproper,f1[3],f2[3],f3[3],f4[3]; double rjisq, rji, rlksq, rlk, cosphi, angfac; double cjiji, clkji, clklk, cfact1, cfact2, cfact3; eimproper = 0.0; if (eflag || vflag) ev_setup(eflag,vflag); else evflag = 0; double **x = atom->x; double **f = atom->f; int **improperlist = neighbor->improperlist; int nimproperlist = neighbor->nimproperlist; int nlocal = atom->nlocal; int newton_bond = force->newton_bond; for (n = 0; n < nimproperlist; n++) { /* Ask the improper list for the atom types. */ i1 = improperlist[n][0]; i2 = improperlist[n][1]; i3 = improperlist[n][2]; i4 = improperlist[n][3]; type = improperlist[n][4]; /* separation vector between i1 and i2, (i2-i1) */ vb1x = x[i2][0] - x[i1][0]; vb1y = x[i2][1] - x[i1][1]; vb1z = x[i2][2] - x[i1][2]; rjisq = vb1x*vb1x + vb1y*vb1y + vb1z*vb1z ; rji = sqrt(rjisq); /* separation vector between i2 and i3 (i3-i2) */ vb2x = x[i3][0] - x[i2][0]; vb2y = x[i3][1] - x[i2][1]; vb2z = x[i3][2] - x[i2][2]; /* separation vector between i3 and i4, (i4-i3) */ vb3x = x[i4][0] - x[i3][0]; vb3y = x[i4][1] - x[i3][1]; vb3z = x[i4][2] - x[i3][2]; rlksq = vb3x*vb3x + vb3y*vb3y + vb3z*vb3z ; rlk = sqrt(rlksq); cosphi = (vb3x*vb1x + vb3y*vb1y + vb3z*vb1z)/(rji * rlk); /* Check that cos(phi) is in the correct limits. */ if (cosphi > 1.0 + TOLERANCE || cosphi < (-1.0 - TOLERANCE)) { int me; MPI_Comm_rank(world,&me); if (screen) { char str[128]; sprintf(str,"Improper problem: %d " BIGINT_FORMAT " " TAGINT_FORMAT " " TAGINT_FORMAT " " TAGINT_FORMAT " " TAGINT_FORMAT, me,update->ntimestep, atom->tag[i1],atom->tag[i2],atom->tag[i3],atom->tag[i4]); error->warning(FLERR,str,0); fprintf(screen," 1st atom: %d %g %g %g\n",me,x[i1][0],x[i1][1],x[i1][2]); fprintf(screen," 2nd atom: %d %g %g %g\n",me,x[i2][0],x[i2][1],x[i2][2]); fprintf(screen," 3rd atom: %d %g %g %g\n",me,x[i3][0],x[i3][1],x[i3][2]); fprintf(screen," 4th atom: %d %g %g %g\n",me,x[i4][0],x[i4][1],x[i4][2]); } } /* Apply corrections to round-off errors. */ if (cosphi > 1.0) cosphi -= SMALL; if (cosphi < -1.0) cosphi += SMALL; /* Calculate the angle: */ double torangle = acos(cosphi); cosphi = cos(torangle - chi[type]); if (eflag) eimproper = 0.5 * k[type] * cosphi * cosphi; /* printf("The tags: %d-%d-%d-%d, of type %d .\n",atom->tag[i1],atom->tag[i2],atom->tag[i3],atom->tag[i4],type); printf("The ji vector: %f, %f, %f.\nThe lk vector: %f, %f, %f.\n", vb1x,vb1y,vb1z,vb3x,vb3y,vb3z); printf("The cosine of the angle: %-1.16e.\n", cosphi); printf("The energy of the improper: %-1.16e with prefactor %-1.16e.\n", eimproper, 0.5*k[type]); */ /* Work out forces. */ angfac = - k[type] * cosphi; cjiji = rjisq; clklk = rlksq; /*CLKJI = RXLK * RXJI + RYLK * RYJI + RZLK * RZJI */ clkji = vb3x*vb1x + vb3y*vb1y + vb3z*vb1z; /*CFACT1 = CLKLK * CJIJI CFACT1 = SQRT(CFACT1) CFACT1 = ANGFAC / CFACT1*/ cfact1 = angfac / sqrt(clklk * cjiji); /*CFACT2 = CLKJI / CLKLK*/ cfact2 = clkji / clklk; /*CFACT3 = CLKJI / CJIJI*/ cfact3 = clkji / cjiji; /*FIX = -RXLK + CFACT3 * RXJI FIY = -RYLK + CFACT3 * RYJI FIZ = -RZLK + CFACT3 * RZJI*/ f1[0] = - vb3x + cfact3 * vb1x; f1[1] = - vb3y + cfact3 * vb1y; f1[2] = - vb3z + cfact3 * vb1z; /*FJX = -FIX FJY = -FIY FJZ = -FIZ*/ f2[0] = - f1[0]; f2[1] = - f1[1]; f2[2] = - f1[2]; /*FKX = CFACT2 * RXLK - RXJI FKY = CFACT2 * RYLK - RYJI FKZ = CFACT2 * RZLK - RZJI*/ f3[0] = cfact2 * vb3x - vb1x; f3[1] = cfact2 * vb3y - vb1y; f3[2] = cfact2 * vb3z - vb1z; /*FLX = -FKX FLY = -FKY FLZ = -FKZ*/ f4[0] = - f3[0]; f4[1] = - f3[1]; f4[2] = - f3[2]; /*FIX = FIX * CFACT1 FIY = FIY * CFACT1 FIZ = FIZ * CFACT1*/ f1[0] *= cfact1; f1[1] *= cfact1; f1[2] *= cfact1; /*FJX = FJX * CFACT1 FJY = FJY * CFACT1 FJZ = FJZ * CFACT1*/ f2[0] *= cfact1; f2[1] *= cfact1; f2[2] *= cfact1; /*FKX = FKX * CFACT1 FKY = FKY * CFACT1 FKZ = FKZ * CFACT1*/ f3[0] *= cfact1; f3[1] *= cfact1; f3[2] *= cfact1; /*FLX = FLX * CFACT1 FLY = FLY * CFACT1 FLZ = FLZ * CFACT1*/ f4[0] *= cfact1; f4[1] *= cfact1; f4[2] *= cfact1; /* Apply force to each of 4 atoms */ if (newton_bond || i1 < nlocal) { f[i1][0] += f1[0]; f[i1][1] += f1[1]; f[i1][2] += f1[2]; } if (newton_bond || i2 < nlocal) { f[i2][0] += f2[0]; f[i2][1] += f2[1]; f[i2][2] += f2[2]; } if (newton_bond || i3 < nlocal) { f[i3][0] += f3[0]; f[i3][1] += f3[1]; f[i3][2] += f3[2]; } if (newton_bond || i4 < nlocal) { f[i4][0] += f4[0]; f[i4][1] += f4[1]; f[i4][2] += f4[2]; } if (evflag) ev_tally(i1,i2,i3,i4,nlocal,newton_bond,eimproper,f1,f3,f4, -vb1x,-vb1y,-vb1z,vb2x,vb2y,vb2z,vb3x,vb3y,vb3z); } } /* ---------------------------------------------------------------------- */ void ImproperCossq::allocate() { allocated = 1; int n = atom->nimpropertypes; memory->create(k,n+1,"improper:k"); memory->create(chi,n+1,"improper:chi"); memory->create(setflag,n+1,"improper:setflag"); for (int i = 1; i <= n; i++) setflag[i] = 0; } /* ---------------------------------------------------------------------- set coeffs for one type ------------------------------------------------------------------------- */ void ImproperCossq::coeff(int narg, char **arg) { /* Check whether there exist sufficient number of arguments. 0: type of improper to be applied to 1: energetic constant 2: equilibrium angle in degrees */ if (narg != 3) error->all(FLERR,"Incorrect args for cossq improper coefficients"); if (!allocated) allocate(); int ilo,ihi; force->bounds(FLERR,arg[0],atom->nimpropertypes,ilo,ihi); double k_one = force->numeric(FLERR,arg[1]); double chi_one = force->numeric(FLERR,arg[2]); int count = 0; for (int i = ilo; i <= ihi; i++) { k[i] = k_one; chi[i] = ((chi_one * MY_PI)/180.0); setflag[i] = 1; count++; } if (count == 0) error->all(FLERR,"Incorrect args for improper coefficients"); } /* ---------------------------------------------------------------------- proc 0 writes out coeffs to restart file ------------------------------------------------------------------------- */ void ImproperCossq::write_restart(FILE *fp) { fwrite(&k[1],sizeof(double),atom->nimpropertypes,fp); fwrite(&chi[1],sizeof(double),atom->nimpropertypes,fp); } /* ---------------------------------------------------------------------- proc 0 reads coeffs from restart file, bcasts them ------------------------------------------------------------------------- */ void ImproperCossq::read_restart(FILE *fp) { allocate(); if (comm->me == 0) { fread(&k[1],sizeof(double),atom->nimpropertypes,fp); fread(&chi[1],sizeof(double),atom->nimpropertypes,fp); } MPI_Bcast(&k[1],atom->nimpropertypes,MPI_DOUBLE,0,world); MPI_Bcast(&chi[1],atom->nimpropertypes,MPI_DOUBLE,0,world); for (int i = 1; i <= atom->nimpropertypes; i++) setflag[i] = 1; } /* ---------------------------------------------------------------------- proc 0 writes to data file ------------------------------------------------------------------------- */ void ImproperCossq::write_data(FILE *fp) { for (int i = 1; i <= atom->nimpropertypes; i++) fprintf(fp,"%d %g %g\n",i,k[i],chi[i]/MY_PI*180.0); }