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 2.0  2   *4    np_   s4e_    120.0000    75.0000
 2.0  2   *4    np_   s_      120.0000    75.0000
 2.0  2   *5    np_   o'_     120.0000    75.0000
 2.0  2   *5    np_   o_      120.0000    75.0000
 2.0  2   *6    np_   n_      120.0000    75.0000
 2.0  2   *7    np_   c3m_    120.0000    75.0000
 2.0  2   *7    np_   c4m_    120.0000    75.0000
 2.0  2   *7    np_   c_      120.0000    75.0000
 2.0  2   *     nt_   *       180.0000    50.0000
 2.0  2   h_    o*_   h_      104.5000    50.0000
 2.0  2   c3m_  o3e_  c3m_     58.9580    60.0000
 2.0  2   c4m_  o4e_  c4m_     91.7370    60.0000
 2.0  2   *     o_    *       109.5000    60.0000
 2.0  2   *1    o_    si_     124.1000    56.4000
 2.0  2   *2    o_    h_      109.0000    58.5000
 2.0  2   *3    o_    f_      109.5000    60.0000
 2.0  2   *4    o_    s'_     109.5000    60.0000
 2.0  2   *4    o_    s3e_    109.5000    60.0000
 2.0  2   *4    o_    s4e_    109.5000    60.0000
 2.0  2   *4    o_    s_      109.5000    60.0000
 2.0  2   *5    o_    o'_     109.5000    60.0000
 2.0  2   *5    o_    o_      109.5000    60.0000
 2.0  2   *6    o_    n3m_    120.0000    72.0000
 2.0  2   *6    o_    n4m_    120.0010    72.0000
 2.0  2   *6    o_    n_      120.0000    72.0000
 2.0  2   *7    o_    c3m_    109.5000    60.0000
 2.0  2   *7    o_    c4m_    109.5000    60.0000
 2.0  2   *7    o_    c_      109.5000    60.0000
 2.0  2   si    o_    si_     149.8000    31.1000
 2.0  2   *     op_   *       108.0000    75.0000
 2.0  2   *1    op_   si_     106.0000    27.5000
 2.0  2   *     p_    *       109.5000    45.0000
 4.0 13   o     p     o       109.5000    45.0000
 2.0  2   *1    p_    si_     109.5000    30.0000
 2.0  2   *2    p_    h_      109.5000    45.0000
 2.0  2   *3    p_    f_      109.5000    45.0000
 2.0  2   *4    p_    s'_     120.0000   100.0000
 2.0  2   *5    p_    s_      109.5000    45.0000
 2.0  2   *6    p_    o'_     120.0000   110.0000
 2.0  2   *7    p_    o_      109.5000    45.0000
 2.0  2   *8    p_    n_      109.5000    45.0000
 2.0  2   *9    p_    c3m_    109.5000    45.0000
 2.0  2   *9    p_    c4m_    109.5000    45.0000
 2.0  2   *9    p_    c_      109.5000    45.0000
 2.0  2   *     s3e_  *       109.5000    75.0000
 2.0  2   *1    s3e_  si_     109.5000    48.0000
 2.0  2   *2    s3e_  h_      112.0000    31.8000
 2.0  2   *3    s3e_  f_      109.5000    75.0000
 2.0  2   *4    s3e_  s'_     109.5000    75.0000
 2.0  2   *4    s3e_  s3e_    103.5000    75.0000
 2.0  2   *4    s3e_  s4e_    103.5000    75.0000
 2.0  2   *4    s3e_  s_      109.5000    75.0000
 2.0  2   *5    s3e_  o'_     113.1000    42.3000
 2.0  2   *5    s3e_  o_      113.1000    42.3000
 2.0  2   *6    s3e_  n3m_    113.1000    42.3000
 2.0  2   *6    s3e_  n4m_    113.1000    42.3000
 2.0  2   *6    s3e_  n_      113.1000    42.3000
 2.0  2   *7    s3e_  c3m_     99.0000    58.0000
 2.0  2   *7    s3e_  c4m_     99.0000    58.0000
 2.0  2   *7    s3e_  c_       99.0000    58.0000
 2.0  2   c3m_  s3e_  c3m_     44.5000    58.0000
 2.0  2   *     s4e_  *       109.5000    75.0000
 2.0  2   *1    s4e_  si_     109.5000    48.0000
 2.0  2   *2    s4e_  h_      112.0000    31.8000
 2.0  2   *3    s4e_  f_      109.5000    75.0000
 2.0  2   *4    s4e_  s'_     109.5000    75.0000
 2.0  2   *4    s4e_  s3e_    103.5000    75.0000
 2.0  2   *4    s4e_  s4e_    103.5000    75.0000
 2.0  2   *4    s4e_  s_      109.5000    75.0000
 2.0  2   *5    s4e_  o'_     113.1000    42.3000
 2.0  2   *5    s4e_  o_      113.1000    42.3000
 2.0  2   *6    s4e_  n3m_    113.1000    42.3000
 2.0  2   *6    s4e_  n4m_    113.1000    42.3000
 2.0  2   *6    s4e_  n_      113.1000    42.3000
 2.0  2   *7    s4e_  c3m_     99.0000    58.0000
 2.0  2   *7    s4e_  c4m_     99.0000    58.0000
 2.0  2   *7    s4e_  c_       99.0000    58.0000
 2.0  2   c4m_  s4e_  c4m_     85.9200    58.0000
 2.0  2   *     s_    *       109.5000    50.0000
 2.0  2   *1    s_    si_     109.5000    48.0000
 2.0  2   *2    s_    h_      112.0000    31.8000
 2.0  2   *3    s_    f_      109.5000    75.0000
 2.0  2   *4    s_    s'_     109.5000    75.0000
 2.0  2   *4    s_    s3e_    103.5000    75.0000
 2.0  2   *4    s_    s4e_    103.5000    75.0000
 2.0  2   *4    s_    s_      103.5000    75.0000
 2.0  2   *5    s_    o'_     113.1000    42.3000
 2.0  2   *5    s_    o_      113.1000    42.3000
 2.0  2   *6    s_    n3m_    113.1000    42.3000
 2.0  2   *6    s_    n4m_    113.1000    42.3000
 2.0  2   *6    s_    n_      113.1000    42.3000
 2.0  2   *7    s_    c3m_     99.0000    58.0000
 2.0  2   *7    s_    c4m_     99.0000    58.0000
 2.0  2   *7    s_    c_      102.0000    58.0000
 2.0  2   *     si_   *       113.5000    44.4000
 2.0  2   *1    si_   si_     113.4000    33.3000
 2.0  2   *2    si_   h_      112.0000    31.8000
 2.0  2   *3    si_   f_      117.3000    44.1000
 2.0  2   *4    si_   s_      113.1000    42.3000
 2.0  2   *5    si_   o_      113.1000    42.3000
 2.0  2   *6    si_   n_      113.5000    44.4000
 2.0  2   *7    si_   c3m_    113.5000    44.4000
 2.0  2   *7    si_   c4m_    113.5000    44.4000
 2.0  2   *7    si_   c_      113.5000    44.4000
 2.0  2   *     sp_   *        92.5670   120.0000
 2.0  2   *1    sp_   si_      96.0000    48.0000
 2.0  2   *2    sp_   h_       96.0000    48.0000
 2.0  2   *3    sp_   f_       92.5670   126.5060
 2.0  2   *4    sp_   s'_      92.5670   126.5060
 2.0  2   *4    sp_   s_       92.5670   126.5060
 2.0  2   *5    sp_   o'_      92.5670   126.5060
 2.0  2   *5    sp_   o_       92.5670   126.5060
 2.0  2   *6    sp_   n_       92.5670   126.5060
 2.0  2   *7    sp_   c3m_     92.5670   126.5060
 2.0  2   *7    sp_   c4m_     92.5670   126.5060
 2.0  2   *7    sp_   c_       92.5670   126.5060


#quartic_angle        cff91

> Delta = Theta - Theta0
> E = K2 * Delta^2  +  K3 * Delta^3  +  K4 * Delta^4

!Ver Ref    I     J     K      Theta0       K2         K3         K4
!--- ---  ----- ----- -----   --------   --------   --------   --------
 3.0 10   oah   az    oah     119.5540    56.2161    67.5146    75.6704
 3.0 10   oah   az    oas     135.8500     1.5716   -23.2602    24.2341
 3.0 10   oah   az    ob       96.9383    41.2978   -101.1850   180.8230
 3.0 10   oas   az    oas     114.1500   112.9470   -37.6330    22.7467
 3.0 10   oas   az    ob       97.0360    73.0531   -31.9551     5.5982
 3.0 10   ob    az    ob       97.0360    73.0531   -31.9551     5.5982
 2.1  8   br    c     br      109.6985    71.9700     0.0000     0.0000
 2.1  8   br    c     c       109.1026    64.7730     0.0000     0.0000
 2.1  8   br    c     cl      111.6408    71.9700     0.0000     0.0000
 2.1  8   br    c     f       109.1026    71.9700     0.0000     0.0000
 2.1  8   br    c     h       106.9999    46.0608     0.0000     0.0000
 1.0  1   c     c     c       112.6700    39.5160    -7.4430    -9.5583
 1.0  1   c     c     c-      104.4900    31.3750    -4.4023    -6.5271
 1.0  1   c     c     c=      111.7600    45.7026   -10.6396    -9.9121
 1.0  1   c     c     c=1     111.7600    45.7026   -10.6396    -9.9121
 1.0  1   c     c     c=2     111.7600    45.7026   -10.6396    -9.9121
 1.0  1   c     c     c_0     108.4000    43.9594    -8.3924    -9.3379
 2.1  8   c     c     c_1     108.5295    51.9747    -9.4851   -10.9985
 2.1  8   c     c     cl      107.0000    61.1745     0.0000     0.0000
 1.3  1   c     c     cp      108.4000    43.9594    -8.3924    -9.3379
 2.1  8   c     c     f       109.2000    68.3715     0.0000     0.0000
 1.0  1   c     c     h       110.7700    41.4530   -10.6040     5.1290
 1.0  1   c     c     n       114.3018    42.6589   -10.5464    -9.3243
 1.0  1   c     c     n+      112.1300    66.4520     4.8694    37.7860
 1.1  1   c     c     n=      117.2847    55.4431     0.0000     0.0000
 2.1  7   c     c     n_2     109.8300    76.8966   -48.7334    18.0162
 1.0  1   c     c     na      111.9100    60.7147   -13.3366   -13.0785
 1.0  1   c     c     nr      117.3500    55.0400     0.0000     0.0000
 1.0  1   c     c     o       111.2700    54.5381    -8.3642   -13.0838
 2.1  6   c     c     o_2     107.4100    63.3907   -13.4513     1.6650
 2.0  5   c     c     oz      105.4100    63.3907   -13.4513     0.0000
 1.0  1   c     c     s       112.5642    47.0276   -10.6790   -10.1687
 2.2  9   c     c     si      112.6700    39.5160    -7.4430     0.0000
 1.0  1   c-    c     h       109.6700    37.9190    -7.3877    -8.0694
 1.3  1   c-    c     n       100.5663    52.0966    -5.2642   -10.7045
 1.0  1   c=    c     c=      113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=    c     c=1     113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=    c     c=2     113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=    c     h       110.0600    41.2784   -14.2963     5.2229
 1.0  1   c=1   c     c=1     113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=1   c     c=2     113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=1   c     h       110.0600    41.2784   -14.2963     5.2229
 1.0  1   c=2   c     c=2     113.0100    44.2251   -10.2683    -9.5886
 1.0  1   c=2   c     h       110.0600    41.2784   -14.2963     5.2229
 1.0  1   c_0   c     cp      108.4000    43.9594    -8.3924    -9.3379
 1.0  1   c_0   c     h       107.8594    38.0833   -17.5074     0.0000
 1.0  1   c_0   c     o       106.1764    74.4143   -12.6018   -48.7850
 2.1  8   c_1   c     h       107.7336    40.6099   -28.8121     0.0000
 1.0  1   c_1   c     n       100.5663    52.0966    -5.2642   -10.7045
 1.3  1   c_1   c     n+      100.5663    52.0966    -5.2642   -10.7045
 2.1  8   cl    c     cl      111.6408    71.9700     0.0000     0.0000
 2.1  8   cl    c     f       109.1026    71.9700     0.0000     0.0000
 2.1  8   cl    c     h       107.9968    51.0987     0.0000     0.0000
 1.5  4   cp    c     cp      111.0000    44.3234    -9.4454     0.0000
 1.0  1   cp    c     h       111.0000    44.3234    -9.4454     0.0000
 2.1  8   f     c     f       109.1026    71.9700     0.0000     0.0000
 2.1  8   f     c     h       108.5010    57.5760     0.0000     0.0000
 1.0  1   h     c     h       107.6600    39.6410   -12.9210    -2.4318
 1.0  1   h     c     n       108.9372    57.4010     2.9374     0.0000
 1.0  1   h     c     n+      105.8500    72.2630   -28.1923     0.0000
 1.1  1   h     c     n=      107.4989    62.7484     0.0000     0.0000
 1.1  1   h     c     n=1     107.4989    62.7484     0.0000     0.0000
 1.1  1   h     c     n=2     107.4989    62.7484     0.0000     0.0000
 2.1  7   h     c     n_2     108.5330    66.9202   -13.6480    10.3280
 1.0  1   h     c     na      110.6204    51.3137    -6.7198    -2.6003
 1.0  1   h     c     nr      107.5000    62.6790     0.0000     0.0000
 1.0  1   h     c     o       108.7280    58.5446   -10.8088   -12.4006
 2.1  6   h     c     o_2     107.6880    65.4801   -10.3498     5.8866
 2.0  5   h     c     oz      107.6880    70.4801   -10.3498     0.0000
 1.0  1   h     c     s       107.8522    51.4949   -13.5270     7.0260
 2.2  9   h     c     si      112.0355    28.7721   -13.9523     0.0000
 1.0  4   h     c     sio     111.5360    30.2481   -15.5255     0.0000
 1.0  1   s     c     s       111.5000    27.9677     0.0000     0.0000
 1.0  1   nr    c+    nr      117.4500    83.9840     0.0000     0.0000
 1.0  1   c     c-    o-      115.0600    59.0960   -15.1430   -12.9820
 1.0  1   h     c-    o-      112.7500    61.1530   -14.0190   -13.2380
 1.0  1   o-    c-    o-      130.0100   111.2900   -52.3390   -28.1070
 1.0  1   c     c=    c       121.0100    29.2704   -10.1175    -6.7906
 1.0  1   c     c=    c=      126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=    c=1     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=    c=2     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=    h       117.2700    30.0944    -8.0826    -8.6781
 3.1 12   c=    c=    c=      117.6000    56.4800   -16.2283   -12.6333
 3.1 12   c=    c=    c_1     121.1000    66.1100   -22.0206   -15.2133
 1.0  1   c=    c=    h       124.8800    35.2766   -17.7740    -1.6215
 3.1 12   c=    c=    n_2     121.0000    55.9100   -18.5471   -12.8549
 1.0  1   c=1   c=    h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   c=2   c=    h       124.8800    35.2766   -17.7740    -1.6215
 3.1 12   c_1   c=    h       120.3000    35.7000   -11.5062    -8.1591
 1.0  1   h     c=    h       115.4900    29.6363   -12.4853    -6.2218
 3.1 12   h     c=    n_2     115.7000    38.2900   -10.1050    -8.4480
 2.1  8   o-    c=    o-      180.0000   200.0000     0.0000     0.0000
 2.1  8   s'    c=    s'      180.0000    70.0000     0.0000     0.0000
 1.0  1   c     c=1   c       121.0100    29.2704   -10.1175    -6.7906
 1.0  1   c     c=1   c=      126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=1   c=1     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=1   c=2     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=1   h       117.2700    30.0944    -8.0826    -8.6781
 1.0  1   c=    c=1   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   c=1   c=1   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   c=2   c=1   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   h     c=1   h       115.4900    29.6363   -12.4853    -6.2218
 1.0  1   c     c=2   c       121.0100    29.2704   -10.1175    -6.7906
 1.0  1   c     c=2   c=      126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=2   c=1     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=2   c=2     126.2600    43.8250   -27.7266     1.0056
 1.0  1   c     c=2   h       117.2700    30.0944    -8.0826    -8.6781
 1.0  1   c=    c=2   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   c=1   c=2   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   c=2   c=2   h       124.8800    35.2766   -17.7740    -1.6215
 1.0  1   h     c=2   h       115.4900    29.6363   -12.4853    -6.2218
 1.0  1   c     c_0   c       110.5884    34.6214    -7.0939    -7.4032
 1.0  1   c     c_0   cp      110.5884    34.6214    -7.0939    -7.4032
 1.0  1   c     c_0   h       106.2000    27.4878    -1.9350    14.5545
 1.0  1   c     c_0   o_1     119.3000    65.1016   -17.9766     0.0000
 1.0  1   cp    c_0   cp      110.5884    34.6214    -7.0939    -7.4032
 1.0  1   cp    c_0   h       106.2000    27.4878    -1.9350    14.5545
 1.0  1   cp    c_0   o_1     119.3000    65.1016   -17.9766     0.0000
 1.0  1   h     c_0   h       108.6000    40.0764    -6.8139    -8.4349
 1.0  1   h     c_0   o_1     116.5000    59.6420   -21.9179     0.0000
 2.1  8   c     c_1   n_2     116.9257    39.4193   -10.9945    -8.7733
 2.1  8   c     c_1   o_1     123.1451    55.5431   -17.2123     0.1348
 2.1  8   c     c_1   o_2     100.3182    38.8631    -3.8323    -7.9802
 3.1 12   c=    c_1   n_2     113.6000    41.1200    -9.8283    -8.9479
 3.1 12   c=    c_1   o_1     125.9000    46.0600   -18.5463   -11.0998
 2.1  8   cp    c_1   n_2     108.4400    84.8377   -19.9640     2.7405
 2.1  6   cp    c_1   o_1     125.5320    72.3167   -16.0650     2.0818
 2.1  6   cp    c_1   o_2     108.4400    84.8377   -19.9640     2.7405
 2.1  8   h     c_1   n_2     110.3935    52.1647   -18.4845     0.0000
 2.1  8   h     c_1   o_1     117.8326    45.9187   -22.5264     0.0000
 2.1  8   h     c_1   o_2     110.5209    32.3751    -0.6174    -6.5639
 1.0  1   n     c_1   n       122.5292   104.0857   -36.7315   -24.2616
 1.0  1   n     c_1   o_1     125.5420    92.5720   -34.4800   -11.1871
 2.1  8   n_2   c_1   o_1     125.5320   101.8765   -41.8094     0.0000
 1.0  1   o     c_1   o_1     118.9855    98.6813   -22.2485    10.3673
 2.1  6   o_1   c_1   o_2     120.7970    95.3446   -32.2869     6.3778
 2.1  7   n_2   c_2   n_2     114.5292   104.0857   -36.7315    24.2616
 2.1  7   n_2   c_2   o_1     125.5320   101.8765   -41.8094     7.7236
 2.1  7   n_2   c_2   o_2     108.4400   112.4403   -59.9730    38.3067
 2.1  7   o_1   c_2   o_2     120.7970    95.3446   -32.2869     6.3778
 2.1  7   o_2   c_2   o_2     109.4930   137.9111   -39.8755    59.0768
 1.0  1   c     cp    cp      120.0500    44.7148   -22.7352     0.0000
 1.3  1   c     cp    np      120.0500    44.7148   -22.7352     0.0000
 1.0  1   c_0   cp    cp      108.4000    43.9594    -8.3924    -9.3379
 2.1  6   c_1   cp    cp      116.0640    71.2598   -15.8273     2.0506
 1.0  1   cp    cp    cp      118.9000    61.0226   -34.9931     0.0000
 1.0  1   cp    cp    h       117.9400    35.1558   -12.4682     0.0000
 2.1  7   cp    cp    n_2     120.7640    73.2738   -27.4033    13.3920
 1.0  1   cp    cp    nh      112.5900    78.6418   -16.3888     0.0000
 1.0  1   cp    cp    nn      121.4584    61.0647   -21.6172     0.0000
 1.0  1   cp    cp    np      116.5100    76.6970   -35.3868     0.0000
 1.0  1   cp    cp    o       123.4200    73.6781   -21.6787     0.0000
 2.1  6   cp    cp    o_2     117.1400    33.0391   -14.7807     3.8573
 1.0  1   cp    cp    op      104.1700   101.3206   -17.3072     0.0000
 2.0  5   cp    cp    oz      120.1400    33.0391   -14.7807     0.0000
 3.1 12   cp    cp    p=      120.0007    47.8413   -15.2288   -10.9066
 2.2  9   cp    cp    si      120.0000    30.4689   -23.5439     0.0000
 1.0  1   cp    cp    sp      105.5300    96.2006   -44.9267     0.0000
 1.0  1   h     cp    nh      109.8000    43.8408    -9.5153     0.0000
 1.0  1   h     cp    np      110.5500    40.8275   -13.0318     0.0000
 1.0  1   h     cp    op      106.1700    48.0995    -9.0144     0.0000
 1.0  1   h     cp    sp      115.9800    36.7902   -13.1342     0.0000
 1.0  1   nh    cp    nh      105.0080   107.0693   -27.7154     0.0000
 1.0  1   nh    cp    np      108.9100    98.8519    -5.7502     0.0000
 1.0  1   nn    cp    np      118.5414    56.9522    -7.2655     0.0000
 1.0  1   np    cp    np      115.3800    85.4923    -6.5225     0.0000
 1.0  1   np    cp    op      104.0100   104.4800     0.0000     0.0000
 1.0  1   np    cp    sp      114.2300    92.3110   -35.5956     0.0000
 1.1  1   n=    cr    nr      125.5320   101.8765   -41.8094     0.0000
 1.1  1   n=1   cr    nr      125.5320   101.8765   -41.8094     0.0000
 1.1  1   n=2   cr    nr      125.5320   101.8765   -41.8094     0.0000
 1.1  1   nr    cr    nr      122.5292   104.0857   -36.7315   -24.2616
 2.0  5   oo    cz    oz      120.0510    97.3782   -26.5619     0.0000
 2.0  5   oz    cz    oz      109.4930   137.9111   -39.8755    59.0768
 1.0  1   c     n     c       111.5635    39.6084    -8.5459    -8.5152
 1.0  1   c     n     c_1     111.0372    31.8958    -6.6942    -6.8370
 1.0  1   c     n     h*      113.8683    45.9271   -20.0824     0.0000
 3.1 12   c     n     p=      120.0833    25.0010    -6.1167    -5.4570
 1.0  1   c_1   n     c_1     121.9556    76.3105   -26.3166   -17.6944
 1.0  1   c_1   n     h*      117.9607    37.4964    -8.1837     0.0000
 1.0  1   h*    n     h*      116.9402    37.5749    -8.6676     0.0000
 3.1 12   h*    n     p=      114.0833    25.0010    -6.1167    -5.4570
 1.0  1   c     n+    c       109.7700    44.8220    -3.9132     0.0000
 1.0  1   c     n+    h+      110.5100    49.2170   -12.2153   -18.9667
 1.0  1   h+    n+    h+      106.1100    45.3280   -14.0474     1.9350
 1.1  1   c     n=    cr      117.0900    31.6888     0.0000     0.0000
 3.1 12   h*    n=    p=      120.0000    26.0683    -8.2978    -5.9429
 3.1 12   p=    n=    p=      118.2000    36.0683    -7.6881    -5.8576
 2.1  8   c     n_2   c_1     122.7520    60.4647   -29.6188     0.0000
 2.1  7   c     n_2   c_2     122.7520    60.4647   -29.6188     5.3290
 2.1  7   c     n_2   hn2     120.1350    29.2218   -14.1448     7.2380
 3.1 12   c=    n_2   c_1     125.1000    67.5900   -26.3889   -16.1536
 3.1 12   c=    n_2   hn2     120.1000    52.1200   -16.6595   -11.8919
 2.1  8   c_1   n_2   cp      116.6260    42.4711   -10.4269     0.0000
 2.1  8   c_1   n_2   hn2     122.9480    40.4820   -16.2028     0.0000
 2.1  7   c_2   n_2   cp      120.0700    47.1131   -32.5592    13.1257
 2.1  7   c_2   n_2   hn2     122.9480    40.4820   -16.2028     8.3280
 2.1  7   cp    n_2   hn2     116.3230    18.3123    -7.8325     5.3290
 2.1  7   hn2   n_2   hn2     122.3730    27.6081   -10.3291     9.2800
 1.0  1   c     na    c       112.4436    47.2337   -10.6612   -10.2062
 1.0  1   c     na    h*      110.9538    50.8652    -4.4522   -10.0298
 1.0  1   h*    na    h*      107.0671    45.2520    -7.5558    -9.5120
 1.0  1   cp    nh    cp      106.0100   109.7746    -9.0636     0.0000
 1.0  1   cp    nh    h*      109.3800    47.0120   -17.3556     0.0000
 1.0  1   cp    nh    np      109.3900   119.1811     0.0000     0.0000
 1.0  1   h*    nh    np       99.4530    41.6499    -5.7422     0.0000
 1.0  1   cp    nn    h*      111.8725    40.8369   -15.6673     0.0000
 1.0  1   h*    nn    h*      107.5130    42.5182   -21.7566    -4.3372
 1.0  1   cp    np    cp      111.6800    84.5159   -48.5528     0.0000
 1.0  1   cp    np    nh      108.2200   119.0383   -24.2061     0.0000
 1.0  1   cp    np    np      106.0400   109.1158   -42.9319     0.0000
 1.0  1   c     nr    c+      117.0900    31.4400     0.0000     0.0000
 1.0  1   c     nr    h*      117.2000    37.2620     0.0000     0.0000
 1.0  1   c+    nr    h*      119.0700    45.8110     0.0000     0.0000
 1.1  1   cr    nr    h*      122.9480    40.4820   -16.2028     0.0000
 1.0  1   h*    nr    h*      110.9100    31.0910     0.0000     0.0000
 1.0  1   c     o     c       104.5000    35.7454   -10.0067    -6.2729
 1.0  1   c     o     c_1     102.9695    38.9739    -6.2595    -8.1710
 1.4  1   c     o     cp      102.9695    38.9739    -6.2595    -8.1710
 1.0  1   c     o     h*      105.8000    52.7061   -12.1090    -9.8681
 3.1 12   c     o     p=      118.2833    35.0010   -10.3597    -7.8699
 1.0  1   c_1   o     h*      111.2537    53.5303   -11.8454   -11.5405
 1.0  1   cp    o     h*      108.1900    53.1250    -8.5016     0.0000
 3.1 12   h*    o     p=      112.2833    26.0310    -5.8280    -5.6195
 1.2  1   h*    o*    h*      103.7000    49.8400   -11.6000    -8.0000
 2.1  6   c     o_2   c_1     113.2880    61.2868   -28.9786     7.9929
 2.1  7   c     o_2   c_2     113.6200    57.9274   -17.1312    23.5480
 2.1  6   c_1   o_2   cp      113.0700    47.1131   -32.5592    13.1257
 2.1  6   c_1   o_2   ho2     112.8740    53.2512   -14.9979     2.4640
 2.1  7   c_2   o_2   cp      115.0700    47.1131   -32.5592    13.1257
 2.1  7   c_2   o_2   ho2     113.1580    49.6892   -25.9467     5.3280
 3.0 10   az    oah   hoa     129.6770    15.5877   -23.6906     9.7663
 3.0 10   az    oas   sz      167.7890    21.3772    -3.8146     8.1995
 3.0 10   az    ob    hb      106.4920    73.8986   -23.9590     8.0039
 3.0 10   az    ob    sz      139.4630    62.0713   -30.7987    16.6347
 3.0 10   hb    ob    sz      113.0480    26.6270   -29.5879    19.8910
 1.0  1   cp    op    cp      103.4300   112.4497   -25.7326     0.0000
 3.0 10   hos   osh   sz      123.4920    14.8634   -17.2643    57.7495
 1.0  4   h*    osi   sio     122.8880    23.7764   -19.8152     9.6331
 1.0  4   sio   osi   sio     157.0260     9.0740   -19.5576     8.5000
 3.0 10   sz    oss   sz      176.2650    18.8146    37.9749    42.8222
 2.0  5   c     oz    cz      113.6200    57.9274   -17.1312    60.0000
 2.0  5   cp    oz    cz      115.0700    47.1131   -32.5592    13.1257
 2.0  5   cz    oz    ho2     113.1580    49.6892   -25.9467     0.0000
 3.1 12   cl    p=    cl      100.6000    94.7390    -9.6046   -19.4682
 3.1 12   cl    p=    cp      109.9153    75.4619   -13.4603   -16.0981
 3.1 12   cl    p=    f        98.4500   104.3358    -8.2038   -21.3348
 3.1 12   cl    p=    h       100.0557    59.5624    -5.7203   -12.2224
 3.1 12   cl    p=    n        98.8500    90.2538    -7.6919   -18.4787
 3.1 12   cl    p=    n=      119.5000    83.6226   -26.0666   -18.9852
 3.1 12   cl    p=    o        98.0500    91.2538    -7.0872   -18.6603
 3.1 12   cp    p=    cp      119.2306    56.1847   -17.3159   -12.7280
 3.1 12   cp    p=    f       107.7653    85.0587   -12.0595   -17.9646
 3.1 12   cp    p=    h       108.2306    36.1847    -6.4878    -7.6463
 3.1 12   cp    p=    n       108.1653    70.9767   -11.5476   -15.1086
 3.1 12   cp    p=    n=      119.6000    63.0624   -19.7404   -14.3290
 3.1 12   cp    p=    o       107.3653    71.9767   -10.9429   -15.2901
 3.1 12   f     p=    f        96.3000   113.9327    -6.8030   -23.2013
 3.1 12   f     p=    h        99.9197    80.7297    -7.6457   -16.5604
 3.1 12   f     p=    n        96.7000    99.8506    -6.2912   -20.3452
 3.1 12   f     p=    n=      120.0245    99.8462   -31.8145   -22.7669
 3.1 12   f     p=    o        95.9000   100.8506    -5.6865   -20.5268
 3.1 12   h     p=    h       103.4084    39.6953    -5.1338    -8.2266
 3.1 12   h     p=    n       103.9784    68.2569    -9.2212   -14.1736
 3.1 12   h     p=    n=      119.0329    45.9784   -14.0522   -10.3994
 3.1 12   h     p=    o       103.9784    73.2569    -9.8966   -15.2119
 3.1 12   n     p=    n        97.1000    85.7686    -5.7793   -17.4892
 3.1 12   n     p=    n=      123.2153    89.9233   -32.6119   -21.0956
 3.1 12   n     p=    o        96.3000    86.7686    -5.1746   -17.6707
 3.1 12   n=    p=    n=      112.8000    90.5233   -20.8007   -19.6019
 3.1 12   n=    p=    o       120.2153    99.9233   -32.0927   -22.8209
 3.1 12   o     p=    o        95.5000    87.7686    -4.5699   -17.8523
 4.0 13   o     p     o       109.0000    45.0000     0.0000     0.0000
 1.0  1   c     s     c        97.5000    57.6938    -5.0559   -11.8206
 1.0  1   c     s     h        96.8479    56.7336    14.2713     0.0000
 1.0  1   c     s     s       100.3000    57.2900    -6.5301   -11.8204
 1.0  1   h     s     h        94.3711    54.9676     0.0000     0.0000
 1.0  1   h     s     s        97.2876    54.4281     0.0000     0.0000
 2.1  8   o-    s'    o-      119.3290   135.0000     0.0000     0.0000
 2.2  9   c     si    c       113.1855    36.2069   -20.3939    20.0172
 2.2  9   c     si    h       112.0977    36.4832   -12.8094     0.0000
 2.2  9   c     si    si      113.0000    19.4692   -34.3471     0.0000
 2.2  9   cp    si    h       109.5932    41.9497   -42.3639    48.1442
 2.2  9   h     si    h       108.6051    32.5415    -8.3164     0.0000
 2.2  9   h     si    si      112.0893    22.5062   -11.5926     0.0000
 2.2  9   si    si    si      114.2676    24.9501   -19.5949     0.0000
 1.0  4   c     sio   c       114.9060    23.0218   -31.3993    24.9814
 1.0  4   c     sio   h       110.1810    38.5645   -17.8735     0.0000
 1.0  4   c     sio   osi     114.9060    23.0218   -31.3993    24.9814
 1.0  4   h     sio   h       106.0360    48.9872    -9.1607     0.0000
 1.0  4   h     sio   osi     107.3550    57.6643   -10.6506     4.6274
 1.0  4   osi   sio   osi     110.6930    70.3069    -6.9375     0.0000
 1.0  1   cp    sp    cp       88.2540   130.6992   -18.4789     0.0000
 3.0 10   oas   sz    oas     104.4940    83.7103   -97.1839    16.9574
 3.0 10   oas   sz    ob      104.4940    83.7103   -97.1839    16.9574
 3.0 10   oas   sz    osh     119.3400    28.1962   -64.3068     4.7117
 3.0 10   oas   sz    oss     108.3940   127.0520   -16.5736     0.0000
 3.0 10   ob    sz    ob      104.4940    83.7103   -97.1839    16.9574
 3.0 10   ob    sz    osh     107.3310    79.2578   -46.7537   108.6900
 3.0 10   ob    sz    oss     104.4940    83.7103   -97.1839    16.9574
 3.0 10   osh   sz    osh     115.0310    68.3381    49.4314   116.2400
 3.0 10   osh   sz    oss     110.6700   117.5060   -49.8921     0.0000
 3.0 10   oss   sz    oss     110.6120   154.1860   -68.6595    23.6292


#torsion_1            cff91_auto

> E = Kphi * [ 1 + cos(n*Phi - Phi0) ]

!Ver Ref    I     J     K     L       KPhi     n     Phi0
!--- ---  ----- ----- ----- -----   --------  ---  ---------
 2.0  2   *     c'_   c'_   *         0.4500    2   180.0000
 2.0  2   *     c'_   c=_   *         0.4500    2   180.0000
 2.0  3   *     c'_   c=_1  *         0.4500    2   180.0000
 2.0  3   *     c'_   c=_2  *         0.4500    2   180.0000
 2.0  3   *     c'_   c=_3  *         0.4500    2   180.0000
 2.0  2   *     c'_   c_    *         0.0000    0     0.0000
 2.0  2   *     c'_   cp_   *         2.5000    2   180.0000
 2.0  2   *     c'_   ct_   *         0.0000    0     0.0000
 2.0  2   *     c'_   n3n_  *         0.7000    2   180.0000
 2.0  2   *     c'_   n=_   *         0.9000    2   180.0000
 2.0  3   *     c'_   n=_1  *         0.9000    2   180.0000
 2.0  3   *     c'_   n=_2  *         0.9000    2   180.0000
 2.0  3   *     c'_   n=_3  *         0.9000    2   180.0000
 2.0  2   *     c'_   n_    *         3.2000    2   180.0000
 2.0  2   *     c'_   n_    h_        1.2000    2   180.0000
 2.0  2   *     c'_   np_   *         5.0000    2   180.0000
 2.0  2   *     c'_   np_   h         1.0000    2   180.0000
 2.0  2   *     c'_   o_    *         2.2500    2   180.0000
 2.0  2   *     c'_   op_   *         2.2500    2   180.0000
 2.0  2   *     c'_   s_    *         1.5000    2   180.0000
 2.0  2   *     c'_   si_   *         0.0000    0     0.0000
 2.0  2   *     c'_   sp_   *         1.5000    2   180.0000
 2.0  2   *     c+_   n_    *         3.4000    2   180.0000
 2.0  2   *     c=_   c=_   *         4.0750    2   180.0000
 2.0  2   *     c=_   c_    *         0.2110    3     0.0000
 2.0  2   *     c=_   cp_   *         0.5000    2   180.0000
 2.0  2   *     c=_   ct_   *         0.0000    0     0.0000
 2.0  2   *     c=_   n3n_  *         0.5000    2   180.0000
 2.0  2   *     c=_   n=_   *         8.1500    2   180.0000
 2.0  2   *     c=_   n_    *         1.2500    2   180.0000
 2.0  2   *     c=_   na_   *         0.0000    0     0.0000
 2.0  2   *     c=_   np_   *         1.5000    2   180.0000
 2.0  2   *     c=_   np_   h_        0.7500    2   180.0000
 2.0  2   *     c=_   o_    *         0.9000    2   180.0000
 2.0  2   *     c=_   op_   *         4.0000    2   180.0000
 2.0  2   *     c=_   p_    *         1.2500    2   180.0000
 2.0  2   *     c=_   s_    *         1.5000    2   180.0000
 2.0  2   *     c=_   si_   *         0.2110    3     0.0000
 2.0  2   *     c=_   sp_   *         6.0000    2   180.0000
 2.0  3   *     c=_1  c=_1  *         0.6250    2   180.0000
 2.0  3   *     c=_1  c=_2  *         0.6250    2   180.0000
 2.0  3   *     c=_1  c=_3  *         4.0750    2   180.0000
 2.0  3   *     c=_1  c_    *         0.2110    3     0.0000
 2.0  3   *     c=_1  cp_   *         0.5000    2   180.0000
 2.0  3   *     c=_1  ct_   *         0.0000    0     0.0000
 2.0  3   *     c=_1  n3n_  *         0.7000    2   180.0000
 2.0  3   *     c=_1  n=_1  *         0.6250    2   180.0000
 2.0  3   *     c=_1  n=_2  *         0.6250    2   180.0000
 2.0  3   *     c=_1  n=_3  *         8.1500    2   180.0000
 2.0  3   *     c=_1  n_    *         1.2500    2   180.0000
 2.0  3   *     c=_1  na_   *         0.0000    0     0.0000
 2.0  3   *     c=_1  np_   *         1.5000    2   180.0000
 2.0  3   *     c=_1  np_   h_        0.7500    2   180.0000
 2.0  3   *     c=_1  o_    *         0.9000    2   180.0000
 2.0  3   *     c=_1  op_   *         4.0000    2   180.0000
 2.0  3   *     c=_1  p_    *         1.2500    2   180.0000
 2.0  3   *     c=_1  s_    *         1.5000    2   180.0000
 2.0  3   *     c=_1  si_   *         0.2110    3     0.0000
 2.0  3   *     c=_1  sp_   *         6.0000    2   180.0000
 2.0  3   *     c=_2  c=_2  *         3.0000    2   180.0000
 2.0  3   *     c=_2  c=_3  *         0.6250    2   180.0000
 2.0  3   *     c=_2  c_    *         0.2110    3     0.0000
 2.0  3   *     c=_2  cp_   *         0.5000    2   180.0000
 2.0  3   *     c=_2  ct_   *         0.0000    0     0.0000
 2.0  3   *     c=_2  n3n_  *         0.7000    2   180.0000
 2.0  3   *     c=_2  n=_1  *         0.6250    2   180.0000
 2.0  3   *     c=_2  n=_2  *         2.5000    2   180.0000
 2.0  3   *     c=_2  n=_3  *         0.6250    2   180.0000
 2.0  3   *     c=_2  n_    *         1.2500    2   180.0000
 2.0  3   *     c=_2  na_   *         0.0000    0     0.0000
 2.0  3   *     c=_2  np_   *         1.5000    2   180.0000
 2.0  3   *     c=_2  np_   h_        0.7500    2   180.0000
 2.0  3   *     c=_2  o_    *         0.9000    2   180.0000
 2.0  3   *     c=_2  op_   *         4.0000    2   180.0000
 2.0  3   *     c=_2  p_    *         1.2500    2   180.0000
 2.0  3   *     c=_2  s_    *         1.5000    2   180.0000
 2.0  3   *     c=_2  si_   *         0.2110    3     0.0000
 2.0  3   *     c=_2  sp_   *         6.0000    2   180.0000
 2.0  3   *     c=_3  c=_3  *         4.0750    2   180.0000
 2.0  3   *     c=_3  c_    *         0.2110    3     0.0000
 2.0  3   *     c=_3  cp_   *         0.5000    2   180.0000
 2.0  3   *     c=_3  ct_   *         0.0000    0     0.0000
 2.0  3   *     c=_3  n3n_  *         0.7000    2   180.0000
 2.0  3   *     c=_3  n=_1  *         8.1500    2   180.0000
 2.0  3   *     c=_3  n=_2  *         0.6250    2   180.0000
 2.0  3   *     c=_3  n=_3  *         8.1500    2   180.0000
 2.0  3   *     c=_3  n_    *         1.2500    2   180.0000
 2.0  3   *     c=_3  na_   *         0.0000    0     0.0000
 2.0  3   *     c=_3  np_   *         1.5000    2   180.0000
 2.0  3   *     c=_3  np_   h_        0.7500    2   180.0000
 2.0  3   *     c=_3  o_    *         0.9000    2   180.0000
 2.0  3   *     c=_3  op_   *         4.0000    2   180.0000
 2.0  3   *     c=_3  p_    *         1.2500    2   180.0000
 2.0  3   *     c=_3  s_    *         1.5000    2   180.0000
 2.0  3   *     c=_3  si_   *         0.2110    3     0.0000
 2.0  3   *     c=_3  sp_   *         6.0000    2   180.0000
 2.0  2   *     c_    c_    *         0.1580    3     0.0000
 2.0  2   *     c_    cp_   *         0.0000    0     0.0000
 2.0  2   *     c_    ct_   *         0.0000    0     0.0000
 2.0  2   *     c_    n3n_  *         0.0500    3     0.0000
 2.0  2   *     c_    n=_   *         0.0000    0     0.0000
 2.0  3   *     c_    n=_1  *         0.0000    0     0.0000
 2.0  3   *     c_    n=_2  *         0.0000    0     0.0000
 2.0  3   *     c_    n=_3  *         0.0000    0     0.0000
 2.0  2   *     c_    n_    *         0.0000    0     0.0000
 2.0  2   *     c_    na_   *         0.0500    3     0.0000
 2.0  2   *     c_    np_   *         0.0000    0     0.0000
 2.0  2   *     c_    o_    *         0.1300    3     0.0000
 2.0  2   *     c_    p_    *         0.0000    0     0.0000
 2.0  2   *     c_    s_    *         0.1367    3     0.0000
 2.0  2   *     c_    si_   *         0.1111    3     0.0000
 2.0  2   *     cp_   cp_   *         3.0000    2   180.0000
 2.0  2   *     cp_   ct_   *         0.0000    0     0.0000
 2.0  2   *     cp_   n3n_  *         0.5000    2   180.0000
 2.0  2   *     cp_   n=_   *         1.2500    2   180.0000
 2.0  3   *     cp_   n=_1  *         1.2500    2   180.0000
 2.0  3   *     cp_   n=_2  *         1.2500    2   180.0000
 2.0  3   *     cp_   n=_3  *         1.2500    2   180.0000
 2.0  2   *     cp_   n_    *         2.2500    2   180.0000
 2.0  2   *     cp_   na_   *         2.2500    2   180.0000
 2.0  2   *     cp_   np_   *         2.0000    2   180.0000
 2.0  2   *     cp_   np_   h_        1.0000    2   180.0000
 2.0  2   *     cp_   o_    *         1.8000    2   180.0000
 2.0  2   *     cp_   o_    h_        0.7500    2   180.0000
 2.0  2   *     cp_   op_   *         6.0000    2   180.0000
 2.0  2   *     cp_   p_    *         0.2500    3     0.0000
 2.0  2   *     cp_   s_    *         1.5000    2   180.0000
 2.0  2   *     cp_   si_   *         0.1667    3     0.0000
 2.0  2   *     cp_   sp_   *         6.0000    2   180.0000
 2.0  2   *     ct_   ct_   *         0.0000    0     0.0000
 2.0  2   *     ct_   n3n_  *         0.0000    0     0.0000
 2.0  2   *     ct_   n_    *         0.0000    0     0.0000
 2.0  2   *     ct_   na_   *         0.0000    0     0.0000
 2.0  2   *     ct_   np_   *         0.0000    0     0.0000
 2.0  2   *     ct_   o_    *         0.0000    0     0.0000
 2.0  2   *     ct_   s_    *         0.0000    0     0.0000
 2.0  2   *     ct_   si_   *         0.0000    0     0.0000
 2.0  2   *     n3n_  n3n_  *         0.0500    2   180.0000
 2.0  2   *     n3n_  n=_   *         0.0500    2   180.0000
 2.0  3   *     n3n_  n=_1  *         0.0500    2   180.0000
 2.0  3   *     n3n_  n=_2  *         0.0500    2   180.0000
 2.0  3   *     n3n_  n=_3  *         0.0500    2   180.0000
 2.0  2   *     n3n_  n_    *         0.0500    2   180.0000
 2.0  2   *     n3n_  na_   *         0.0000    0     0.0000
 2.0  2   *     n3n_  np_   *         0.0500    2   180.0000
 2.0  2   *     n3n_  o_    *         0.3000    3     0.0000
 2.0  2   *     n3n_  s_    *         0.3000    2     0.0000
 2.0  2   *     n3n_  si_   *         0.0500    3     0.0000
 2.0  2   *     n=_   n=_   *        15.0000    2   180.0000
 2.0  2   *     n=_   n_    *         0.7500    2   180.0000
 2.0  2   *     n=_   na_   *         0.0000    0     0.0000
 2.0  2   *     n=_   np_   *         1.5000    2   180.0000
 2.0  2   *     n=_   np_   h_        0.7500    2   180.0000
 2.0  2   *     n=_   o_    *         0.7000    2   180.0000
 2.0  2   *     n=_   s_    *         0.7000    2   180.0000
 2.0  2   *     n=_   si_   *         0.2333    2   180.0000
 2.0  3   *     n=_1  n=_1  *         1.5000    2   180.0000
 2.0  3   *     n=_1  n=_2  *         1.5000    2   180.0000
 2.0  3   *     n=_1  n=_3  *        15.0000    2   180.0000
 2.0  3   *     n=_1  n_    *         0.7500    2   180.0000
 2.0  3   *     n=_1  na_   *         0.0000    0     0.0000
 2.0  3   *     n=_1  np_   *         1.5000    2   180.0000
 2.0  3   *     n=_1  np_   h_        0.7500    2   180.0000
 2.0  3   *     n=_1  o_    *         0.7000    2   180.0000
 2.0  3   *     n=_1  s_    *         0.7000    2   180.0000
 2.0  3   *     n=_1  si_   *         0.2333    2   180.0000
 2.0  3   *     n=_2  n=_2  *         7.5000    2   180.0000
 2.0  3   *     n=_2  n=_3  *         1.5000    2   180.0000
 2.0  3   *     n=_2  n_    *         0.7500    2   180.0000
 2.0  3   *     n=_2  na_   *         0.0000    0     0.0000
 2.0  3   *     n=_2  np_   *         1.5000    2   180.0000
 2.0  3   *     n=_2  np_   h_        0.7500    2   180.0000
 2.0  3   *     n=_2  o_    *         0.7000    2   180.0000
 2.0  3   *     n=_2  s_    *         0.7000    2   180.0000
 2.0  3   *     n=_2  si_   *         0.2333    2   180.0000
 2.0  3   *     n=_3  n=_3  *        15.0000    2   180.0000
 2.0  3   *     n=_3  n_    *         0.7500    2   180.0000
 2.0  3   *     n=_3  na_   *         0.0000    0     0.0000
 2.0  3   *     n=_3  np_   *         1.5000    2   180.0000
 2.0  3   *     n=_3  np_   h_        0.7500    2   180.0000
 2.0  3   *     n=_3  o_    *         0.7000    2   180.0000
 2.0  3   *     n=_3  s_    *         0.7000    2   180.0000
 2.0  3   *     n=_3  si_   *         0.2333    2   180.0000
 2.0  2   *     n_    n_    *         0.3750    2   180.0000
 2.0  2   *     n_    na_   *         0.0000    0     0.0000
 2.0  2   *     n_    np_   *         0.7500    2   180.0000
 2.0  2   *     n_    np_   h_        0.3750    2   180.0000
 2.0  2   *     n_    o_    *         0.5000    2   180.0000
 2.0  2   *     n_    s_    *         0.5000    2   180.0000
 2.0  2   *     n_    si_   *         0.0000    0     0.0000
 2.0  2   *     na_   na_   *         0.2500    3     0.0000
 2.0  2   *     na_   np_   *         0.0000    0     0.0000
 2.0  2   *     na_   o_    *         0.0975    3     0.0000
 2.0  2   *     na_   s_    *         0.0975    3     0.0000
 2.0  2   *     na_   si_   *         0.0667    3     0.0000
 2.0  2   *     np_   np_   *        11.0000    2   180.0000
 2.0  2   *     np_   np_   h_        5.5000    2   180.0000
 2.0  2   *     np_   o_    *         1.0000    2   180.0000
 2.0  2   h_    np_   o_    *         0.5000    2   180.0000
 2.0  2   *     np_   op_   *        11.0000    2   180.0000
 2.0  2   h_    np_   op_   *         5.5000    2   180.0000
 2.0  2   *     np_   s_    *         1.0000    2   180.0000
 2.0  2   h_    np_   s_    *         0.5000    2   180.0000
 2.0  2   *     np_   si_   *         0.2500    2   180.0000
 2.0  2   h_    np_   si_   *         0.1250    2   180.0000
 2.0  2   *     np_   sp_   *        10.0000    2   180.0000
 2.0  2   h_    np_   sp_   *         5.5000    2   180.0000
 2.0  2   *     o_    o_    *         1.0000    3     0.0000
 2.0  2   *     o_    p_    *         0.3750    3     0.0000
 2.0  2   *     o_    s_    *         1.0000    3     0.0000
 2.0  2   *     o_    si_   *         0.3333    3     0.0000
 2.0  2   *     p_    s_    *         0.3750    3     0.0000
 2.0  2   *     p_    si_   *         0.0000    3     0.0000
 2.0  2   *     s_    s_    *         5.5000    2     0.0000
 2.0  2   *     s_    si_   *         0.2333    3     0.0000
 2.0  2   *     si_   si_   *         0.1667    3     0.0000


#torsion_3            cff91

> E = SUM(n=1,3) { V(n) * [ 1 + cos(n*Phi - Phi0(n)) ] }

!Ver Ref    I     J     K     L       V(1)    Phi1(0)    V(2)    Phi2(0)    V(3)    Phi3(0)
!--- ---  ----- ----- ----- -----   --------  -------  --------  -------  --------  -------
 3.0 10   oah   az    oah   hoa      0.2821      0.0   -0.0644      0.0    0.0752      0.0
 3.0 10   oas   az    oah   hoa      0.0574      0.0   -0.3288      0.0    0.1277      0.0
 3.0 10   ob    az    oah   hoa     -0.7542      0.0   -0.7885      0.0   -0.3199      0.0
 3.0 10   oah   az    oas   sz       1.5821      0.0    2.8457      0.0    0.8378      0.0
 3.0 10   oas   az    oas   sz      -4.8417      0.0   -0.6233      0.0   -1.7530      0.0
 3.0 10   ob    az    oas   sz      -0.0282      0.0    5.2299      0.0   -1.6555      0.0
 3.0 10   oah   az    ob    hb       8.3762      0.0    0.4366      0.0   -0.2767      0.0
 3.0 10   oah   az    ob    sz       1.1339      0.0   -0.4378      0.0    0.2658      0.0
 3.0 10   oas   az    ob    hb       6.7872      0.0    1.7367      0.0    0.1690      0.0
 3.0 10   oas   az    ob    sz      -0.5306      0.0   -1.2578      0.0   -0.1954      0.0
 3.0 10   ob    az    ob    hb       6.7872      0.0    1.7367      0.0    0.1690      0.0
 3.0 10   ob    az    ob    hoa     -0.7542      0.0   -0.7885      0.0   -0.3199      0.0
 3.0 10   ob    az    ob    sz      -0.5306      0.0   -1.2578      0.0   -0.1954      0.0
 2.1  8   br    c     c     br       0.0000      0.0    0.0000      0.0   -0.2000      0.0
 2.1  8   br    c     c     c        0.0000      0.0    0.0000      0.0    0.1500      0.0
 2.1  8   br    c     c     cl       0.0000      0.0    0.0000      0.0   -0.2000      0.0
 2.1  8   br    c     c     f        0.0000      0.0    0.0000      0.0   -0.2000      0.0
 2.1  8   br    c     c     h        0.0000      0.0    0.0000      0.0   -0.2000      0.0
 2.1  8   c     c     c     c        0.0000      0.0    0.0514      0.0   -0.1430      0.0
 1.0  1   c     c     c     c        0.1223      0.0    0.0514      0.0   -0.2230      0.0
 1.0  1   c     c     c     c-      -0.4054      0.0    0.4825      0.0    0.4345      0.0
 1.0  1   c     c     c     c=       0.0883      0.0    0.0000      0.0   -0.0198      0.0
 1.0  1   c     c     c     c=1      0.0883      0.0    0.0000      0.0   -0.0198      0.0
 1.0  1   c     c     c     c=2      0.0883      0.0    0.0000      0.0   -0.0198      0.0
 2.1  8   c     c     c     c_0      0.0929      0.0    0.0689      0.0   -0.2466      0.0
 2.1  8   c     c     c     c_1      0.0972      0.0    0.0722      0.0   -0.2581      0.0
 2.1  8   c     c     c     cl       0.0000      0.0    0.0000      0.0    0.1500      0.0
 2.1  8   c     c     c     f        0.0000      0.0    0.0000      0.0    0.1500      0.0
 2.1  8   c     c     c     h        0.0000      0.0    0.0316      0.0   -0.1681      0.0
 1.0  1   c     c     c     h        0.0000      0.0    0.0316      0.0   -0.1781      0.0
 1.0  1   c     c     c     n        0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.0  1   c     c     c     n+      -1.9394      0.0    0.0086      0.0    0.2775      0.0
 1.1  1   c     c     c     n=       0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.1  1   c     c     c     n=1      0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.1  1   c     c     c     n=2      0.0972      0.0    0.0722      0.0   -0.2581      0.0
 2.1  7   c     c     c     n_2      0.0000      0.0    0.0000      0.0   -0.1441      0.0
 1.0  1   c     c     c     na       0.1764      0.0    0.1766      0.0   -0.5206      0.0
 1.0  1   c     c     c     o        0.7137      0.0    0.2660      0.0   -0.2545      0.0
 2.1  6   c     c     c     o_2      0.0000      0.0    0.0000      0.0   -0.2500      0.0
 2.0  5   c     c     c     oz      -3.6896      0.0    0.0000      0.0    0.0000      0.0
 1.0  1   c     c     c     s       -0.7017      0.0    0.0201      0.0    0.1040      0.0
 2.2  9   c     c     c     si       0.0000      0.0    0.0514      0.0   -0.1430      0.0
 1.3  1   c-    c     c     c_1      0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.3  1   c-    c     c     cp       0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.0  1   c-    c     c     h       -1.2767      0.0    0.5949      0.0    0.2379      0.0
 1.3  1   c-    c     c     n        0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.0  1   c=    c     c     c=       0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=    c     c     c=1      0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=    c     c     c=2      0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=    c     c     h        0.0000      0.0    0.0000      0.0   -0.1166      0.0
 1.0  1   c=1   c     c     c=1      0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=1   c     c     c=2      0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=1   c     c     h        0.0000      0.0    0.0000      0.0   -0.1166      0.0
 1.0  1   c=2   c     c     c=2      0.0000      0.0    0.0000      0.0   -0.3160      0.0
 1.0  1   c=2   c     c     h        0.0000      0.0    0.0000      0.0   -0.1166      0.0
 2.1  8   c_0   c     c     c_0     -1.2352      0.0   -0.2551      0.0   -0.1335      0.0
 1.3  1   c_0   c     c     c_1     -1.2352      0.0   -0.2551      0.0   -0.1335      0.0
 2.1  8   c_0   c     c     cp       0.0929      0.0    0.0689      0.0   -0.2466      0.0
 2.1  8   c_0   c     c     h       -0.1569      0.0   -0.2030      0.0   -0.1599      0.0
 1.3  1   c_0   c     c     n        0.0972      0.0    0.0722      0.0   -0.2581      0.0
 2.1  8   c_0   c     c     o       -0.0858      0.0   -0.1320      0.0   -0.5909      0.0
 1.0  1   c_1   c     c     c_1      0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.3  1   c_1   c     c     cp       0.0972      0.0    0.0722      0.0   -0.2581      0.0
 2.1  8   c_1   c     c     h       -0.0228      0.0    0.0280      0.0   -0.1863      0.0
 1.0  1   c_1   c     c     n        0.0972      0.0    0.0722      0.0   -0.2581      0.0
 1.3  1   c_1   c     c     o       -0.0858      0.0   -0.1320      0.0   -0.5909      0.0
 1.3  1   c_1   c     c     s        0.0972      0.0    0.0722      0.0   -0.2581      0.0
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 2.1  8   cl    c     c     f        0.0000      0.0    0.0000      0.0   -0.1000      0.0
 2.1  8   cl    c     c     h        0.0000      0.0    0.0000      0.0   -0.1000      0.0
 1.3  1   cp    c     c     h       -0.0228      0.0    0.0280      0.0   -0.1863      0.0
 1.3  1   cp    c     c     n        0.0972      0.0    0.0722      0.0   -0.2581      0.0
 2.2  9   cp    c     c     si       0.0000      0.0    0.0514      0.0   -0.1430      0.0
 2.1  8   f     c     c     f        0.0000      0.0    0.0000      0.0   -0.1000      0.0
 2.1  8   f     c     c     h        0.0000      0.0    0.0000      0.0   -0.1000      0.0
 2.1  8   h     c     c     h       -0.1432      0.0    0.0617      0.0   -0.1083      0.0
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 1.0  1   h     c     c     n       -0.0228      0.0    0.0280      0.0   -0.1863      0.0
 1.0  1   h     c     c     n+      -0.2179      0.0   -0.4127      0.0   -0.1252      0.0
 1.1  1   h     c     c     n=      -0.0228      0.0    0.0280      0.0   -0.1863      0.0
 1.1  1   h     c     c     n=1     -0.0228      0.0    0.0280      0.0   -0.1863      0.0
 1.1  1   h     c     c     n=2     -0.0228      0.0    0.0280      0.0   -0.1863      0.0
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 1.0  1   h     c     c     o       -0.1435      0.0    0.2530      0.0   -0.0905      0.0
 2.1  6   h     c     c     o_2      0.0000      0.0    0.0000      0.0   -0.2500      0.0
 2.0  5   h     c     c     oz      -3.6896      0.0    0.0000      0.0    0.0000      0.0
 1.0  1   h     c     c     s       -0.2078      0.0   -0.1060      0.0   -0.3595      0.0
 2.2  9   h     c     c     si       0.0000      0.0    0.0514      0.0   -0.1430      0.0
 1.3  1   n     c     c     o       -0.1820      0.0   -0.1084      0.0   -0.7047      0.0
 1.3  1   n     c     c     s        0.0972      0.0    0.0722      0.0   -0.2581      0.0
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 2.1  7   n_2   c     c     o_2      0.0000      0.0    0.0000      0.0   -0.1441      0.0
 1.0  1   na    c     c     na       0.3805      0.0    0.3547      0.0   -0.1102      0.0
 1.0  1   o     c     c     o       -0.1820      0.0   -0.1084      0.0   -0.7047      0.0
 2.1  6   o_2   c     c     o_2     -0.6070      0.0    0.0060      0.0   -0.1441      0.0
 2.0  5   oz    c     c     oz      -0.6070      0.0    0.0060      0.0   -0.1441      0.0
 1.0  1   s     c     c     s       -1.2002      0.0   -1.2999      0.0   -0.1626      0.0
 1.0  1   c     c     c-    o-       1.7311      0.0    1.8510      0.0   -0.1933      0.0
 1.0  1   h     c     c-    o-      -2.5999      0.0    1.0488      0.0   -0.2089      0.0
 1.3  1   n     c     c-    o-       0.0899      0.0    0.1220      0.0    0.0905      0.0
 1.0  1   c     c     c=    c       -0.0871      0.0    0.0619      0.0   -0.7371      0.0
 1.0  1   c     c     c=    c=       0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=    c=1      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=    c=2      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=    h       -0.2433      0.0    0.0000      0.0   -0.3281      0.0
 1.0  1   c=    c     c=    c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=    c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=    c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=    h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=1   c     c=    c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=    c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=    c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=    h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=2   c     c=    c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=    c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=    c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=    h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   h     c     c=    c       -0.1143      0.0    0.0000      0.0   -0.1682      0.0
 1.0  1   h     c     c=    c=       0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=    c=1      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=    c=2      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=    h       -0.1143      0.0    0.0000      0.0   -0.1349      0.0
 1.0  1   c     c     c=1   c       -0.0871      0.0    0.0619      0.0   -0.7371      0.0
 1.0  1   c     c     c=1   c=       0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=1   c=1      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=1   c=2      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=1   h       -0.2433      0.0    0.0000      0.0   -0.3281      0.0
 1.0  1   c=    c     c=1   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=1   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=1   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=1   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=1   c     c=1   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=1   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=1   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=1   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=2   c     c=1   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=1   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=1   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=1   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   h     c     c=1   c       -0.1143      0.0    0.0000      0.0   -0.1682      0.0
 1.0  1   h     c     c=1   c=       0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=1   c=1      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=1   c=2      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=1   h       -0.1143      0.0    0.0000      0.0   -0.1349      0.0
 1.0  1   c     c     c=2   c       -0.0871      0.0    0.0619      0.0   -0.7371      0.0
 1.0  1   c     c     c=2   c=       0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=2   c=1      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=2   c=2      0.2433      0.0    0.0000      0.0    0.1040      0.0
 1.0  1   c     c     c=2   h       -0.2433      0.0    0.0000      0.0   -0.3281      0.0
 1.0  1   c=    c     c=2   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=2   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=2   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=    c     c=2   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=1   c     c=2   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=2   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=2   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=1   c     c=2   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   c=2   c     c=2   c=       0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=2   c=1      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=2   c=2      0.0025      0.0    0.0000      0.0    0.0173      0.0
 1.0  1   c=2   c     c=2   h        0.0025      0.0    0.0000      0.0   -0.2911      0.0
 1.0  1   h     c     c=2   c       -0.1143      0.0    0.0000      0.0   -0.1682      0.0
 1.0  1   h     c     c=2   c=       0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=2   c=1      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=2   c=2      0.1143      0.0    0.0000      0.0    0.1854      0.0
 1.0  1   h     c     c=2   h       -0.1143      0.0    0.0000      0.0   -0.1349      0.0
 2.1  8   c     c     c_0   c        0.2904      0.0    1.0177      0.0   -0.1085      0.0
 2.1  8   c     c     c_0   cp       0.2904      0.0    1.0177      0.0   -0.1085      0.0
 2.1  8   c     c     c_0   h        0.3055      0.0    0.6703      0.0   -0.2816      0.0
 2.1  8   c     c     c_0   o_1      0.6989      0.0    1.2089      0.0   -0.0445      0.0
 2.1  8   cp    c     c_0   o_1      0.6989      0.0    1.2089      0.0   -0.0445      0.0
 2.1  8   h     c     c_0   c       -0.4768      0.0    0.6051      0.0   -0.1205      0.0
 2.1  8   h     c     c_0   cp      -0.4768      0.0    0.6051      0.0   -0.1205      0.0
 2.1  8   h     c     c_0   h       -0.5265      0.0    0.3627      0.0   -0.1792      0.0
 2.1  8   h     c     c_0   o_1     -0.9975      0.0    0.9060      0.0   -0.0195      0.0
 1.0  1   o     c     c_0   h       -0.0390      0.0    1.4052      0.0    0.0757      0.0
 1.0  1   o     c     c_0   o_1      0.6444      0.0    0.7897      0.0    1.0604      0.0
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 2.1  8   c     c     c_1   o_1      0.0442      0.0    0.0292      0.0    0.0562      0.0
 2.1  8   c     c     c_1   o_2      1.8341      0.0    2.0603      0.0   -0.0195      0.0
 2.1  8   h     c     c_1   n_2      0.1693      0.0   -0.0090      0.0   -0.0687      0.0
 2.1  8   h     c     c_1   o_1     -0.1804      0.0    0.0012      0.0    0.0371      0.0
 2.1  8   h     c     c_1   o_2     -0.6359      0.0    1.4807      0.0   -0.0438      0.0
 1.0  1   n     c     c_1   n       -0.0892      0.0    0.1259      0.0   -0.0884      0.0
 1.0  1   n     c     c_1   o_1      0.0899      0.0    0.1220      0.0    0.0905      0.0
 1.3  1   n+    c     c_1   n       -0.0892      0.0    0.1259      0.0   -0.0884      0.0
 1.3  1   n+    c     c_1   o_1      0.0899      0.0    0.1220      0.0    0.0905      0.0
 1.3  1   c     c     cp    cp      -0.2802      0.0   -0.0678      0.0   -0.0122      0.0
 1.3  1   c     c     cp    np      -0.2802      0.0   -0.0678      0.0   -0.0122      0.0
 1.5  1   cp    c     cp    cp      -0.2802      0.0   -0.0678      0.0   -0.0122      0.0
 2.0  1   h     c     cp    cp      -0.2801      0.0   -0.0678      0.0   -0.0122      0.0
 1.0  1   h     c     cp    cp      -0.2802      0.0   -0.0678      0.0   -0.0122      0.0
 1.3  1   h     c     cp    np      -0.2802      0.0   -0.0678      0.0   -0.0122      0.0
 1.0  1   c     c     n     c       -0.0017      0.0   -0.0072      0.0    0.0008      0.0
 1.0  1   c     c     n     c_1      0.0143      0.0   -0.0132      0.0    0.0091      0.0
 1.0  1   c     c     n     h*      -0.0483      0.0   -0.0077      0.0   -0.0014      0.0
 1.3  1   c-    c     n     c_1     -0.0688      0.0    0.0762      0.0   -0.0618      0.0
 1.3  1   c-    c     n     h*       0.0546      0.0    0.0756      0.0    0.0728      0.0
 1.0  1   c_1   c     n     c       -0.0036      0.0    0.0049      0.0    0.0039      0.0
 1.0  1   c_1   c     n     c_1     -0.0688      0.0    0.0762      0.0   -0.0618      0.0
 1.0  1   c_1   c     n     h*       0.0546      0.0    0.0756      0.0    0.0728      0.0
 1.0  1   h     c     n     c        0.0406      0.0    0.0354      0.0   -0.1649      0.0
 1.0  1   h     c     n     c_1      0.0219      0.0   -0.0260      0.0    0.0714      0.0
 1.0  1   h     c     n     h*      -0.0148      0.0   -0.0791      0.0   -0.0148      0.0
 1.0  1   c     c     n+    c        0.7077      0.0   -0.3744      0.0   -0.1914      0.0
 1.0  1   c     c     n+    h+      -0.8792      0.0   -0.5978      0.0   -0.3242      0.0
 1.3  1   c_0   c     n+    h+      -0.8792      0.0   -0.5978      0.0   -0.3242      0.0
 1.3  1   c_1   c     n+    h+      -0.8792      0.0   -0.5978      0.0   -0.3242      0.0
 1.0  1   h     c     n+    c        0.3624      0.0    0.1012      0.0   -0.2486      0.0
 1.0  1   h     c     n+    h+      -0.2458      0.0   -0.2789      0.0   -0.0294      0.0
 1.1  1   c     c     n=    cr       0.0143      0.0   -0.0132      0.0    0.0091      0.0
 1.1  1   h     c     n=    cr       0.5865      0.0   -0.5482      0.0   -0.2767      0.0
 1.1  1   c     c     n=1   cr       0.0143      0.0   -0.0132      0.0    0.0091      0.0
 1.1  1   h     c     n=1   cr       0.5865      0.0   -0.5482      0.0   -0.2767      0.0
 1.1  1   c     c     n=2   cr       0.0143      0.0   -0.0132      0.0    0.0091      0.0
 1.1  1   h     c     n=2   cr       0.5865      0.0   -0.5482      0.0   -0.2767      0.0
 2.1  7   c     c     n_2   c_1      0.0000      0.0    0.0000      0.0   -0.2263      0.0
 2.1  7   c     c     n_2   c_2      0.0000      0.0    0.0000      0.0   -0.2263      0.0
 2.1  7   c     c     n_2   hn2      0.0000      0.0    0.0000      0.0   -0.3263      0.0
 2.1  7   h     c     n_2   c_1      0.0000      0.0    0.0000      0.0   -0.2263      0.0
 2.1  7   h     c     n_2   c_2      0.0000      0.0    0.0000      0.0   -0.2263      0.0
 2.1  7   h     c     n_2   hn2      0.0000      0.0    0.0000      0.0   -0.3263      0.0
 1.0  1   c     c     na    c       -0.1406      0.0    0.4168      0.0    0.0150      0.0
 1.0  1   c     c     na    h*      -1.1506      0.0   -0.6344      0.0   -0.1845      0.0
 1.0  1   h     c     na    c        0.1904      0.0   -0.1342      0.0   -0.2460      0.0
 1.0  1   h     c     na    h*      -0.5187      0.0   -0.4837      0.0   -0.1692      0.0
 1.0  1   c     c     nr    c+      -5.4418      0.0   -0.0437      0.0    0.8035      0.0
 1.0  1   c     c     nr    h*      -5.0724      0.0   -0.4980      0.0   -0.4381      0.0
 1.0  1   h     c     nr    c+       2.8272      0.0   -0.3930      0.0   -0.3847      0.0
 1.0  1   h     c     nr    h*       1.2659      0.0   -0.7739      0.0    0.0378      0.0
 1.0  1   c     c     o     c       -0.5203      0.0   -0.3028      0.0   -0.3450      0.0
 1.0  1   c     c     o     c_0      0.1302      0.0   -0.3250      0.0    0.1134      0.0
 1.0  1   c     c     o     h*      -0.6732      0.0   -0.4778      0.0   -0.1670      0.0
 1.0  1   c_0   c     o     c_0     -1.8534      0.0    0.1981      0.0    0.2423      0.0
 1.0  1   h     c     o     c        0.5302      0.0    0.0000      0.0   -0.3966      0.0
 1.0  1   h     c     o     c_0      0.9513      0.0    0.1155      0.0    0.0720      0.0
 1.4  1   h     c     o     cp       0.9513      0.0    0.1155      0.0    0.0720      0.0
 1.0  1   h     c     o     h*       0.1863      0.0   -0.4338      0.0   -0.2121      0.0
 2.1  6   c     c     o_2   c_1      0.0000      0.0    0.0000      0.0   -0.1932      0.0
 2.1  7   c     c     o_2   c_2      0.0000      0.0    0.0000      0.0   -0.0882      0.0
 2.1  6   c_1   c     o_2   c_1      0.0000      0.0    0.0000      0.0   -0.1932      0.0
 2.1  6   h     c     o_2   c_1      0.0000      0.0    0.0000      0.0   -0.1932      0.0
 2.1  7   h     c     o_2   c_2      0.0000      0.0    0.0000      0.0   -0.0882      0.0
 2.0  5   c     c     oz    cz       0.0000      0.0    0.0000      0.0   -0.1932      0.0
 2.0  5   h     c     oz    cz       0.0000      0.0    0.0000      0.0   -0.1932      0.0
 2.0  5   oz    c     oz    cz       0.0000      0.0    0.0000      0.0   -0.1932      0.0
 1.0  1   c     c     s     c       -0.5073      0.0    0.0155      0.0   -0.0671      0.0
 1.0  1   c     c     s     h       -0.4871      0.0   -0.4514      0.0   -0.1428      0.0
 1.0  1   c     c     s     s       -0.6269      0.0   -0.9598      0.0   -0.4957      0.0
 1.0  1   h     c     s     c       -0.3338      0.0   -0.0684      0.0   -0.1706      0.0
 1.0  1   h     c     s     h       -0.5374      0.0   -0.5091      0.0   -0.1361      0.0
 1.0  1   h     c     s     s       -0.0610      0.0   -0.6387      0.0   -0.3072      0.0
 1.0  1   s     c     s     c       -1.9835      0.0   -1.9213      0.0   -0.3816      0.0
 1.0  1   s     c     s     h       -0.0591      0.0   -0.6235      0.0   -0.0788      0.0
 2.2  9   c     c     si    c        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   c     c     si    cp       0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   c     c     si    h        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   c     c     si    si      -0.3500      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   cp    c     si    c        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   cp    c     si    cp       0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   cp    c     si    h        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   cp    c     si    si       0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   h     c     si    c        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   h     c     si    cp       0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   h     c     si    h        0.0000      0.0    0.0000      0.0   -0.0657      0.0
 2.2  9   h     c     si    si       0.0000      0.0    0.0000      0.0   -0.0657      0.0
 1.0  4   h     c     sio   c       -1.3513      0.0    0.0000      0.0   -0.0580      0.0
 1.0  4   h     c     sio   h       -0.9301      0.0    0.0000      0.0   -0.1259      0.0
 1.0  4   h     c     sio   osi     -1.3513      0.0    0.0000      0.0   -0.0580      0.0
 1.0  1   nr    c+    nr    c       -0.6197      0.0    3.0539      0.0    0.1861      0.0
 1.0  1   nr    c+    nr    h*      -7.2378      0.0    1.9150      0.0    0.1436      0.0
 1.0  1   c     c=    c=    c        0.0860      0.0    5.1995      0.0    0.0000      0.0
 1.0  1   c     c=    c=    h        0.0000      0.0    5.2097      0.0    0.0000      0.0
 1.0  1   h     c=    c=    h        0.0000      0.0    4.8974      0.0    0.0000      0.0
 1.0  1   c     c=    c=1   c        0.0860      0.0    5.1995      0.0    0.0000      0.0
 1.0  1   c     c=    c=1   h        0.0000      0.0    5.2097      0.0    0.0000      0.0
 1.0  1   h     c=    c=1   c        0.0000      0.0    5.2097      0.0    0.0000      0.0
 1.0  1   h     c=    c=1   h        0.0000      0.0    4.8974      0.0    0.0000      0.0
 1.0  1   c     c=    c=2   c        0.0860      0.0    5.1995      0.0    0.0000      0.0
 1.0  1   c     c=    c=2   h        0.0000      0.0    5.2097      0.0    0.0000      0.0
 1.0  1   h     c=    c=2   c        0.0000      0.0    5.2097      0.0    0.0000      0.0
 1.0  1   h     c=    c=2   h        0.0000      0.0    4.8974      0.0    0.0000      0.0
 2.1  8   o_1   c_0   cp    cp       0.0000      0.0    0.9063      0.0    0.0000      0.0
 1.0  1   o_1   c_0   o     c        0.8905      0.0    3.2644      0.0    0.2646      0.0
 2.1  8   n_2   c_1   cp    cp       0.0000      0.0    0.9063      0.0    0.0000      0.0
 2.1  6   o_1   c_1   cp    cp       0.0000      0.0    0.9063      0.0    0.0000      0.0
 2.1  6   o_2   c_1   cp    cp       0.0000      0.0    0.9063      0.0    0.0000      0.0
 1.0  1   h     c_1   n     c_1      0.1907      0.0    1.1212      0.0    0.0426      0.0
 1.0  1   n     c_1   n     h*      -0.7358      0.0    0.4643      0.0   -1.1098      0.0
 1.0  1   o_1   c_1   n     c        0.8297      0.0    3.7234      0.0   -0.0495      0.0
 1.0  1   o_1   c_1   n     c_1     -0.4066      0.0    1.2513      0.0   -0.7507      0.0
 1.0  1   o_1   c_1   n     h*      -1.6938      0.0    2.7386      0.0   -0.3360      0.0
 2.1  8   c     c_1   n_2   c       -0.7532      0.0    2.7392      0.0    0.0907      0.0
 2.1  8   c     c_1   n_2   hn2     -0.8236      0.0    2.1467      0.0   -0.2142      0.0
 2.1  8   cp    c_1   n_2   c       -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  8   cp    c_1   n_2   cp      -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  8   cp    c_1   n_2   hn2     -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  8   h     c_1   n_2   c        0.3345      0.0    2.5838      0.0   -0.4006      0.0
 2.1  8   h     c_1   n_2   hn2     -0.0078      0.0    2.6186      0.0   -0.0900      0.0
 2.1  7   o_1   c_1   n_2   c        0.0000      0.0    2.0521      0.0    0.0000      0.0
 2.1  7   o_1   c_1   n_2   cp       0.0000      0.0    2.0521      0.0    0.0000      0.0
 2.1  7   o_1   c_1   n_2   hn2      0.0000      0.0    2.0521      0.0    0.0000      0.0
 1.0  1   o_1   c_1   o     h*      -2.7332      0.0    2.9646      0.0   -0.0155      0.0
 2.1  8   *     c_1   o_2   *       -2.5594      0.0    2.2013      0.0    0.0325      0.0
 2.1  8   c     c_1   o_2   c       -2.5594      0.0    2.2013      0.0    0.0325      0.0
 2.1  8   c     c_1   o_2   ho2     -2.9126      0.0    1.0199      0.0   -0.2077      0.0
 2.1  6   c=1   c_1   o_2   ho2     -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  6   cp    c_1   o_2   c       -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  6   cp    c_1   o_2   cp      -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  6   cp    c_1   o_2   ho2     -1.1077      0.0    2.0082      0.0    0.0000      0.0
 2.1  8   h     c_1   o_2   c       -0.9993      0.0    0.2131      0.0   -0.4274      0.0
 2.1  8   h     c_1   o_2   ho2     -1.4540      0.0    0.8387      0.0   -0.4912      0.0
 2.1  6   o_1   c_1   o_2   c        0.0000      0.0    2.2089      0.0    0.0000      0.0
 2.1  6   o_1   c_1   o_2   cp       0.0000      0.0    2.2089      0.0    0.0000      0.0
 2.1  6   o_1   c_1   o_2   ho2      0.0000      0.0    2.2089      0.0    0.0000      0.0
 2.1  7   n_2   c_2   n_2   c       -1.0632      0.0    1.5632      0.0    0.0000      0.0
 2.1  7   n_2   c_2   n_2   cp      -1.0632      0.0    1.5632      0.0    0.0000      0.0
 2.1  7   n_2   c_2   n_2   hn2     -1.0632      0.0    1.5632      0.0    0.0000      0.0
 2.1  7   o_1   c_2   n_2   c        0.0000      0.0    2.0521      0.0    0.0000      0.0
 2.1  7   o_1   c_2   n_2   cp       0.0000      0.0    2.0521      0.0    0.0000      0.0
 2.1  7   o_1   c_2   n_2   hn2      0.0000      0.0    2.0521      0.0    0.0000      0.0
 2.1  7   o_2   c_2   n_2   c       -1.7177      0.0    1.8863      0.0    0.0000      0.0
 2.1  7   o_2   c_2   n_2   cp      -1.7177      0.0    1.8863      0.0    0.0000      0.0
 2.1  7   o_2   c_2   n_2   hn2     -1.7177      0.0    1.8863      0.0    0.0000      0.0
 2.1  7   n_2   c_2   o_2   c       -2.9522      0.0    2.4047      0.0    0.0000      0.0
 2.1  7   n_2   c_2   o_2   cp      -2.9522      0.0    2.4047      0.0    0.0000      0.0
 2.1  7   n_2   c_2   o_2   ho2     -2.9522      0.0    2.4047      0.0    0.0000      0.0
 2.1  7   o_1   c_2   o_2   c        0.0000      0.0    1.8099      0.0    0.0000      0.0
 2.1  7   o_1   c_2   o_2   cp       0.0000      0.0    1.8099      0.0    0.0000      0.0
 2.1  7   o_1   c_2   o_2   ho2      0.0000      0.0    1.8099      0.0    0.0000      0.0
 2.1  7   o_2   c_2   o_2   c       -2.9522      0.0    2.4047      0.0    0.0000      0.0
 2.1  7   o_2   c_2   o_2   cp      -2.9522      0.0    2.4047      0.0    0.0000      0.0
 2.1  7   o_2   c_2   o_2   ho2     -2.9522      0.0    2.4047      0.0    0.0000      0.0
 1.0  1   c     cp    cp    cp       0.0000      0.0    4.4072      0.0    0.0000      0.0
 1.0  1   c     cp    cp    h        0.0000      0.0    1.5590      0.0    0.0000      0.0
 1.3  1   c     cp    cp    nh       0.0000      0.0    3.0202      0.0    0.0000      0.0
 2.1  8   c_0   cp    cp    cp       0.0000      0.0    4.6282      0.0    0.0000      0.0
 2.1  8   c_0   cp    cp    h        0.0000      0.0    2.1670      0.0    0.0000      0.0